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ZINC TRIFLUOROMETHANESULPHONATE

zinc trifluoromethanesulphonate

CAS: 54010-75-2

Molecular Formula: C2F6O6S2Zn

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ZINC TRIFLUOROMETHANESULPHONATE - Names and Identifiers

Name zinc trifluoromethanesulphonate
Synonyms Zn(OTf)2
Zinc trifluoromethylsulfonate
Zinc trifluoromethanesulfonate
ZINC TRIFLUOROMETHANESULFONATE
zinc trifluoromethanesulphonate
ZINC TRIFLUOROMETHANESULPHONATE
Bis(trifluoromethanesulfonato)zinc
zinc bis(trifluoromethanesulfonate)
trifluoro-methanesulfonicacizincsalt
Trifluoromethane sulfonic acid zinc
CAS 54010-75-2
EINECS 258-922-6
InChI InChI=1/CHF3O3S.Zn/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+2/p-1

ZINC TRIFLUOROMETHANESULPHONATE - Physico-chemical Properties

Molecular FormulaC2F6O6S2Zn
Molar Mass363.53
Melting Point≥300°C(lit.)
Water SolubilitySoluble in water and acetonitrile. Slightly soluble in methanol. Insoluble in dichloromethane.
AppearanceWhite powder
ColorWhite to light-gray
BRN4028195
Storage ConditionInert atmosphere,Room Temperature
Stabilityhygroscopic
SensitiveHygroscopic
MDLMFCD00013229
UseReagents commonly used in glycosidation methods; catalyst for the synthesis of dithioketal (dithioketals)

ZINC TRIFLUOROMETHANESULPHONATE - Risk and Safety

Hazard SymbolsC - Corrosive
Corrosive
Risk Codes34 - Causes burns
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDsUN 3261 8/PG 2
WGK Germany3
FLUKA BRAND F CODES3-10
TSCAYes
HS Code29049090
Hazard NoteIrritant/Hygroscopic
Hazard Class8
Packing GroupII

ZINC TRIFLUOROMETHANESULPHONATE - Introduction

Extremely soluble in water
Last Update:2022-10-16 17:26:04

ZINC TRIFLUOROMETHANESULPHONATE - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
Lewis catalyst Zinc trifluoromethanesulfonate is the trifluoromethanesulfonate of zinc. It is usually used as a Lewis acid catalyst, for example for silylation reactions.
Zinc trifluoromethanesulfonate is a white powder. Although it is commercially available, some researchers will prepare it by different methods. For example, it can be prepared by the reaction of trifluoromethanesulfonic acid and metallic zinc in acetone, or by the reaction of zinc carbonate in methanol:
Zn 2 HOTf→Zn (OTf)2 H2 ↑
ZnCO3 2 HOTf→Zn (OTf)2 H2O CO2 ↑ (OTf = CF3SO2)
application acids with higher acid strength than 100% sulfuric acid are called super acids. it is expected that super acids can be used as highly functional acid catalysts in the field of fine chemicals. Trifluoromethane sulfonic acid is one of the super acids. It is different from other strong acids in that it is extremely stable to oxidation and reduction. Based on this characteristic, trifluoromethane sulfonic acid has been used as a super acid catalyst with high acid strength and practical value in many aspects in recent years. In addition, many uses are being developed for its derivatives. Zinc trifluoromethanesulfonate, as an efficient Lewis acid catalyst, has also been widely used in recent years.
Uses Catalyst for dithioketal synthesis; Preferred reagent in Koenigs-Knorr-type glycosidation method; Catalysts for thioketylation of ketones.
Commonly used reagents in glycosidation methods; catalyst for the synthesis of dithioketal (dithioketals)
Last Update:2024-04-10 22:29:15
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ZINC TRIFLUOROMETHANESULPHONATE
1785212-51-2
MOLYBDENUM PENTACHLORIDE
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